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XRD analysis and magnetic properties of nanocrystalline Ni20Co80 alloys

Identifieur interne : 000187 ( Main/Exploration ); précédent : 000186; suivant : 000188

XRD analysis and magnetic properties of nanocrystalline Ni20Co80 alloys

Auteurs : N. Bensebaa [Algérie] ; N. Loudjani [Algérie] ; S. Alleg [Algérie] ; L. Dekhil [Algérie] ; J. J. Sunol [Espagne] ; M. Al Sae [Bahreïn] ; M. Bououdina [Bahreïn]

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RBID : Pascal:14-0047201

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Abstract

The mechanical alloying process has been used to prepare nanocrystalline Ni20Co80 alloy from elemental Ni and Co powders in a planetary ball mill under argon atmosphere. Scanning electron microscopy, X-ray diffraction and magnetic measurements were carried out to investigate morphological, structural, microstructural and magnetic properties changes during the milling process. The interdiffusion of Co and Ni leads to a heterogeneous solid solution with Ni-rich and Co-rich environments after 12 h of milling. The end product is a mixture of a highly disordered structure, fcc-Ni(Co), fcc-Co(Ni) and hcp-Co (Ni) phases having different microstructural and structural parameters. The coercivity, Hc, decreases rapidly up to 3 h of milling to about 58.3 Oe and remains constant on further milling. The saturation magnetization, Ms, value of about 126 emu/g is obtained after 48 h of milling.


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Le document en format XML

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<div type="abstract" xml:lang="en">The mechanical alloying process has been used to prepare nanocrystalline Ni
<sub>20</sub>
Co
<sub>80</sub>
alloy from elemental Ni and Co powders in a planetary ball mill under argon atmosphere. Scanning electron microscopy, X-ray diffraction and magnetic measurements were carried out to investigate morphological, structural, microstructural and magnetic properties changes during the milling process. The interdiffusion of Co and Ni leads to a heterogeneous solid solution with Ni-rich and Co-rich environments after 12 h of milling. The end product is a mixture of a highly disordered structure, fcc-Ni(Co), fcc-Co(Ni) and hcp-Co (Ni) phases having different microstructural and structural parameters. The coercivity, H
<sub>c</sub>
, decreases rapidly up to 3 h of milling to about 58.3 Oe and remains constant on further milling. The saturation magnetization, M
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, value of about 126 emu/g is obtained after 48 h of milling.</div>
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